Isentropic process

Isentropic expansion of an ideal gas was treated in Sect. 3.5. Here, the same process is analyzed without the restriction of ideality. Equation (6.23b) is divided by dv while holding s constant, which produces the relation:

To illustrate the effect of gas nonideality on property changes during an isentropic expansion, the right hand side of Eq (6.30) is evaluated for a Van der Waals gas obeying the equation of state in the form given by Eq (2.5):

Substituting the above EOS into Eq (6.28) yields:

In the limit of low pressure, the specific heats are independent of p (or v) and their difference is the gas constant. The nonideal gas effect on Cv is given by the first equality of Eq (6.26). For the Van der Waals EOS (d 2p/dT2)v = 0, so Cv is not a function of v. Substituting R = CP0 - CV0 , setting Cv = CV0 and using the symbol y for CP0/CV0, the above equation becomes:

Integrating between states 1 and 2 gives:

Was this article helpful?

0 0
Solar Panel Basics

Solar Panel Basics

Global warming is a huge problem which will significantly affect every country in the world. Many people all over the world are trying to do whatever they can to help combat the effects of global warming. One of the ways that people can fight global warming is to reduce their dependence on non-renewable energy sources like oil and petroleum based products.

Get My Free Ebook

Post a comment