Rt

For free-energy minimization, d(G/RT) is set eequal to zero, producing an equation of the same for as Eequation (9.63). In order to simplify the notation, define a dimensionless free energy by gi = gio / RT .

Following the procedure outlined in the preceding section, G is to be minimized subject to the constraints of V and W in Eq (9.62)and the following total-element constraints:

nO replaces V in the general theory and nH corresponds to W. The Lagrange multipliers are Xo and Xh. Equation (9.68) is:

go g2

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